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Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution
https://doi.org/10.14990/00000154
https://doi.org/10.14990/00000154875701e1-0071-4744-b75a-b8b7be72bb67
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
K00106.pdf (653.6 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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| 公開日 | 2015-03-26 | |||||
| タイトル | ||||||
| タイトル | Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution | |||||
| タイトル | ||||||
| タイトル | Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.14990/00000154 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
Matsui, Rie
× Matsui, Rie× Ikeda, Yoshiyuki× Sasaki, Muneo× MATSUI, Rie× IKEDA, Yoshiyuki× SASAKI, Muneo |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Kinetic study was carried out by using stopped-flow method for the Meisenheimer σ-complex formation reaction between 2,4,6-trinitrophenyl chloride (picryl chloride: Pic-Cl) and hydroxide in aqueous cationic micellar solutions of dodecyltrimethylammonium bromide (DTAB), myristyltrimethylammonium bromide (MyTAB) and cetyltrimethyl-ammonium bromide (CTAB) dissolved in aqueous solution, for the purpose of elucidating the influence of the microscopic heterogeneity of reaction field on activation parameters. The reaction rate analysis based on a pseudo-phase ion exchange model led us to a conclusion that on the activation process the enthalpy-entropy compensation relationships worked over the wide range of surfactant concentration, and that, for the reaction occurring at the micellar surface, a reactant molecule effective to the reaction had to move into some restricted direction. | |||||
| 書誌情報 |
甲南大学紀要. 理工学編 en : Memoirs of Konan University. Science and engineering series 巻 55, 号 1, p. 39-51, 発行日 2008-07-31 |
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| 出版者 | ||||||
| 出版者 | 甲南大学 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 13480383 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11561231 | |||||
| 論文ID（NAID） | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 110007124418 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
