{"created":"2023-05-15T14:41:40.688095+00:00","id":159,"links":{},"metadata":{"_buckets":{"deposit":"09b8d1a0-02b8-456a-88f8-97a68fcc6536"},"_deposit":{"created_by":18,"id":"159","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"159"},"status":"published"},"_oai":{"id":"oai:konan-u.repo.nii.ac.jp:00000159","sets":["10:20:46:47"]},"author_link":["548","550","549","545","547","546"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-07-31","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"51","bibliographicPageStart":"39","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"甲南大学紀要. 理工学編"},{"bibliographic_title":"Memoirs of Konan University. Science and engineering series","bibliographic_titleLang":"en"}]}]},"item_10002_description_12":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_description":"110007124418","subitem_description_type":"Other"}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Kinetic study was carried out by using stopped-flow method for the Meisenheimer σ-complex formation reaction between 2,4,6-trinitrophenyl chloride (picryl chloride: Pic-Cl) and hydroxide in aqueous cationic micellar solutions of dodecyltrimethylammonium bromide (DTAB), myristyltrimethylammonium bromide (MyTAB) and cetyltrimethyl-ammonium bromide (CTAB) dissolved in aqueous solution, for the purpose of elucidating the influence of the microscopic heterogeneity of reaction field on activation parameters. The reaction rate analysis based on a pseudo-phase ion exchange model led us to a conclusion that on the activation process the enthalpy-entropy compensation relationships worked over the wide range of surfactant concentration, and that, for the reaction occurring at the micellar surface, a reactant molecule effective to the reaction had to move into some restricted direction.","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.14990/00000154","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"甲南大学"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11561231","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13480383","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsui, Rie"}],"nameIdentifiers":[{"nameIdentifier":"545","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ikeda, Yoshiyuki"}],"nameIdentifiers":[{"nameIdentifier":"546","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sasaki, Muneo"}],"nameIdentifiers":[{"nameIdentifier":"547","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"MATSUI, Rie","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"548","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"IKEDA, Yoshiyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"549","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"SASAKI, Muneo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"550","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-03-26"}],"displaytype":"detail","filename":"K00106.pdf","filesize":[{"value":"653.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"K00106.pdf","url":"https://konan-u.repo.nii.ac.jp/record/159/files/K00106.pdf"},"version_id":"8fccb941-abf7-4b7a-9040-532e493bc9df"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution"},{"subitem_title":"Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"18","path":["47"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-03-26"},"publish_date":"2015-03-26","publish_status":"0","recid":"159","relation_version_is_last":true,"title":["Reaction Kinetics of Meisenheimer σ-Complex Formation between 2,4,6-Trinitrophenyl Chloride and Hydroxide Ion in Cationic Micellar Solution"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-12-19T06:12:56.318538+00:00"}