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Effect of Cationic Micellar Reaction Field on Reaction Kinetics of Meisenheimer σ-Complex Formation between 1,3,5-Trinitrobenzene and Hydroxide Ion
https://doi.org/10.14990/00000144
https://doi.org/10.14990/00000144a66f3b1d-3ee0-4d96-8db7-3e9eb6105de8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
K00096.pdf (681.2 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2015-03-26 | |||||
| タイトル | ||||||
| タイトル | Effect of Cationic Micellar Reaction Field on Reaction Kinetics of Meisenheimer σ-Complex Formation between 1,3,5-Trinitrobenzene and Hydroxide Ion | |||||
| タイトル | ||||||
| タイトル | Effect of Cationic Micellar Reaction Field on Reaction Kinetics of Meisenheimer σ-Complex Formation between 1,3,5-Trinitrobenzene and Hydroxide Ion | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.14990/00000144 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
Matsui, Rie
× Matsui, Rie× Ikeda, Yoshiyuki× Sasaki, Muneo× MATSUI, Rie× IKEDA, Yoshiyuki× SASAKI, Muneo |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Kinetic studies were done by using stopped-flow method for the Meisenheimer σ-complex formation reaction between 1,3,5-trinitrobenzene (TNB) and hydroxide ion in cationic micellar solutions of dodecyl-trimethylammonium bromide (DTAB), myristyltrimethylammonium bromide (MyTAB) and cetyltrimethylammonium bromide (CTAB) dissolved in aqueous solution, for the purpose of elucidating the influence of the microscopic heterogeneity of reaction field. The reaction rate analysis based on a pseudo-phase ion exchange model led us to a conclusion that the partition of reactant molecules between the micelle and water phase, and ion exchange between hydroxide ion and bromide ion existing as counter ions of cationic micellar surface were important. On the activation process, the enthalpy-entropy compensation relationships worked over the wide range of surfactant concentration. The derived isokinetic temperature, T_<iso> revealed that in CTAB the reaction might be of enthalpy-control, and that in MyTAB be of entropy-control. | |||||
| 書誌情報 |
甲南大学紀要. 理工学編 en : Memoirs of Konan University. Science and engineering series 巻 54, 号 2, p. 61-73, 発行日 2007-12-25 |
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| 出版者 | ||||||
| 出版者 | 甲南大学 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 13480383 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11561231 | |||||
| 論文ID（NAID） | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | 110007124414 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
