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化学溶出実験法による海水魚中のリチウムの存在状態解析
https://doi.org/10.14990/00000103
https://doi.org/10.14990/00000103777d17f3-99a2-4a39-9868-b699209689d9
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2015-03-25 | |||||
タイトル | ||||||
タイトル | 化学溶出実験法による海水魚中のリチウムの存在状態解析 | |||||
タイトル | ||||||
タイトル | State Analysis of Lithium in Ocean Fish by Chemical Leaching Experiments | |||||
言語 | en | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | リチウム | |||||
キーワード | ||||||
主題 | 存在状態 | |||||
キーワード | ||||||
主題 | イワシ | |||||
キーワード | ||||||
主題 | マグロ | |||||
キーワード | ||||||
主題 | 化学溶出実験 | |||||
キーワード | ||||||
主題 | 分画 | |||||
キーワード | ||||||
主題 | 炎光分析 | |||||
キーワード | ||||||
主題 | lithium | |||||
キーワード | ||||||
主題 | chemical existing state | |||||
キーワード | ||||||
主題 | anchovy | |||||
キーワード | ||||||
主題 | tuna | |||||
キーワード | ||||||
主題 | chemical leaching experiment | |||||
キーワード | ||||||
主題 | fractionation | |||||
キーワード | ||||||
主題 | flame analysis | |||||
資源タイプ | ||||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.14990/00000103 | |||||
ID登録タイプ | JaLC | |||||
著者 |
玉利, 祐三
× 玉利, 祐三× 土屋, 和幸× Tamari, Yuzo× Tsuchiya, Kazuyuki |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Lithium was contained rich in ocean sardine and anchovy; especially concentrated in the back-bone, head or gill of the fish, which were related with calcium as matrix components. In leaching experiments lithium was softly dissolved from the fish bone by shaking with a 0.1mol/l hydrochloric acid or a 0.1mol/l acetic acid solution after washing and removing the surface sea-water on the fish with water. The lithium leached in the acid solutions and remained to the residue was determined by flame photometry using the atomic absorption spectrophotometer with air-acetylene flame, after the decomposition with nitric-perchloric acid mixture. In the gill, head and back-bone of anchovy, 73, 71 and 71% of total lithium were dissolved with 0.1mol/l hydrochloric acid, respectively. Same leaching results were obtained for calcium; 78〜84% of total calcium were also dissolved with the same leaching solution. The ratio of lithium and calcium dissolved in hydrochloric acid or acetic acid were almost constant to be 3〜8×10^<-5> regardless of the sort of acid, the number of leaching fraction and the part of fish bone, and the ratio in the hydrochloric acid leaching was constant to be 7±2×10^<-5>. Those values was nearly equal to the ratio of 6±2×10^<-5> (n=9) of total lithium content of anchovy. It was, therefore, supposed that lithium was existed in fish bone as calcium compounds which was likely apatite or calcite, or a part of total lithium presented as the complexing component with calcium, which was passed through the dialysis filter less than 10000 as molecular weight. | |||||
書誌情報 |
甲南大学紀要. 理工学編 en : Memoirs of Konan University. Science and engineering series 巻 52, 号 2, p. 223-230, 発行日 2005-12-25 |
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出版者 | ||||||
出版者 | 甲南大学 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13480383 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11561231 | |||||
論文ID(NAID) | ||||||
内容記述タイプ | Other | |||||
内容記述 | 110004793105 | |||||
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内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |